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Preparation and characterization of starch nanocrystals. Jan 15, 2018· Fig. 1 presents the X-ray diffraction (XRD) patterns of pretreated starch with different ball milling times (0, 15, 30, 45, 60, 75, 90 min) after smoothing.Ball milling-15 represents that the raw starch was subjected to a ball mill treatment for 15 min and other annotations are similar.The relative crystallinity (RC) of ...